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- This paper presents the concept of using a polyethene film to address the shortcomings of the conventional solar pond which are low efficiency, short operation time among others. The thermal behavior of a solar pond with a polyethene has been analyzed and compared with that without a polyethene film. The experiments show that: the heat storage layer (LCZ) temperature rising rate was significantly higher than that of single layer porous media solar pond. The polyethene film of thickness 100µm was used. The polyethene film brings about the greenhouse effect where the solar energy that penetrates the film is trapped and improves the efficiency of the storage zone. Results show that the efficiency of a polyethene stabilized pond rises to about 69 % compared to the conventional solar pond with about 52 %.
TrinuclearCu(II) complex was designed and synthesized. The binuclear Cu(II) complex was prepared and then condensed with a mononuclear Cu(II) complex to form trinuclear complex as shown below. All the complexes were characterized by using FTIR and UV-Visible spectral studies. ESR spectra and magnetic moments of the trinuclearCu(II) complex show the presence of antiferromagnetic coupling.The electrochemical properties of these complexes were studied in the range of 0 V to -1.4 V.
The functioning of calcium lignosulfonate (CLS) as the potential inhibitor in the corrosion of mild steel in 0.5 M H2SO4 medium has been studied. The various parameters in connection with the corrosion behaviour of the metal and the inhibitive action of CLS were obtained by weight loss, potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy(SEM) methods. The effect of temperature on the mild steel surface has been reported. The results of the present investigation show that CLS acts as a good inhibitor and it is of mixed type. The mode of action is by the process of adsorption at anodic and cathodic sites. The scanning electron microscopic studies gives the picture of surface morpholog